Quantifying Arctic Methane

The paper 'Ebullition and storm-induced methane release from the East Siberian Arctic Shelf', was published in the journal Nature Geoscience on November 24, 2013.

The paper is dedicated “to the memory of the crew of Russian vessel RV Alexei Kulakovsky”, the 11 people who died when their tugboat perished in efforts to assist the scientists who were measuring methane from a fishing boat.

The research team used methods including drilling into the seabed of the Laptev Sea and sonar to analyse methane releases in the water, seeking to quantify the significant amounts of methane that are bubbling up from the sea bed in the East Siberian Arctic Shelf (ESAS, rectangle on image below), the area with shallow seas north of Siberia covering some 810,800 square miles (2.1 million square kilometers). By comparison, the United States (land and water) covers an area of nearly 10 million square kilometers.

“We have proven that the current state of subsea permafrost is incomparably closer to the thaw point than terrestrial permafrost, and that modern warming does contribute to warming the subsea permafrost,” says Natalia Shakhova, adding that an increase in storminess in the Arctic would further speed up the release of methane.

The scientists estimate, on the basis of the sonar data, that “bubbles escaping the partially thawed permafrost inject 100–630 mg methane square meters daily into the overlying water column”, and suggest that “bubbles and storms facilitate the flux of this methane to the overlying ocean and atmosphere, respectively”.

Some 17 teragrams (Tg or Mt) of methane escapes annually from the ESAS, said Natalia Shakova, lead study author and a biogeochemist at the University of Alaska, Fairbanks. This is an upgrade from the earlier estimate of 8 Tg of annual outgassing from the ESAS (Shakhova et al. 2010).

While including a reference to this earlier paper (Shakhova et al. 2010), the IPCC did give much lower estimates for emissions from all hydrates globally and from permafrost (excl. lakes and wetlands), i.e. 6 and 1 Tg per year, respectively.

And by comparison, IPCC estimates for all global methane emissions from manmade and natural sources go from 526 Tg per year to 852 Tg per year, of which 514 to 785 Tg per year is broken down (mostly by hydroxyl).

Sadly, as discussed in an earlier post, the IPCC has decided NOT to warn people about the danger that methane from hydrates will lead to abrupt climate change within decades. Yet, when entering the data by Shakhova et al. in a spreadsheet, a linear trendline (green line on image below) shows methane release in the ESAS reaching 20 Tg by 2013 and 26 Tg by 2015.

An exponential trendline (red/blue line) shows methane release in the ESAS reaching 22 Tg by 2013 and 36 Tg by 2015. Extending that same exponential trendline further into the future shows methane release in the ESAS reaching 2 Gt by the year 2031 and 50 Gt by the year 2043.

Note that accumulated totals over the years will be much higher than the annual release. While the IPCC gives methane a perturbation lifetime of 12.4 years, this methane will persist in the Arctic for much longer because its release is concentrated in the Arctic where hydroxyl levels are also very low.

Globally, IPCC/NOAA figures suggest that abundance of methane in the atmosphere currently (2013) is 1814 parts per billion (ppb), rising with 5 or 6 ppb annually, and that this rise is caused by a difference of 8 Tg between the methane emitted (548 Tg, top-down estimate) and broken down annually (540 Tg, top-down estimate). It is also worth noting that the IPCC has increased methane's global warming potential to 86 over 20 years with climate-carbon feedbacks, while there are reasons to assume that methane's impact, especially short-term and in case of large abrupt releases in the Arctic, is even stronger. Furthermore, the IPCC now gives methane a Radiative Forcing (RF) of 0.97 W/m^-2 (up from 48 W/m^-2 in 2007 and relative to 1750), as illustrated by the image below.

According to the IPCC, methane levels in 1750 and 2011 were 722 ppb and 1803 ppb, respectively. The total global methane burden is estimated to be about 5 Gt, i.e. 5 petagrams (Pg) or 5,000 Tg. A back-of-envelope calculation sugests that the methane burden in 1750 was 5 Gt x (722 : 1803) = 2 Gt. Furthermore, methane's 0.97 W/m^-2 RF is 42% of the total RF 2.29 W/m^-2. Therefore, the 3 Gt of methane that has been added to the atmosphere since 1750 is responsible for almost half of all the global warming since that time.

For now, the IPCC's estimated annual increase in global methane levels may seem small, but this figure appears to be based on low-altitude data collected over the past few decades. The total methane burden may already be rising much more rapidly, also because methane is rising in the atmosphere, increasing the burden especially at higher altitudes, as evidenced by the increasing occurence of noctilucent clouds. In other words, the 8 Tg estimate may reflect older data related to changes in lower-altitude measurements only, but the total methane burden may well be rising much more rapidly due to increases at higher altitudes. Further analysis comparing satellite data at different altitudes over the years could verify this.

An earlier post estimated that as much as 2.1 Mt (or 2.1 Tg) of methane could have been released abruptly end 2011. If you compare the animation of that earlier post with the recent animation, then current abrupt releases from the sea floor of the Arctic Ocean appear to be even higher.

As said, methane releases from the Arctic Ocean may for now seem small and may not yet make global temperatures rise much, but nonetheless the methane cloud hanging over the Arctic is contributing to warming locally. Combined with the increased likelyhood of extreme weather and rapid loss of ice and snow cover in the Arctic, this could make water temperatures in the Arctic Ocean rise even further, causing further destabilization of methane hydrates. Furthermore, the mechanical force of methane release from hydrates (rapidly expanding 160 times in volume) itself can also contribute to hydrate destabilization. Seismic activity could also lead to destabilization. Indeed, there are many factors that could contribute to exponential rise of methane release from the Arctic Ocean, as discussed in the post on methane hydrates, which calls for comprehensive and effective action, such as discussed at the Climate Plan blog.


References

Ebullition and storm-induced methane release from the East Siberian Arctic Shelf, by Natalia Shakhova, Igor Semiletov, Ira Leifer, Valentin Sergienko, Anatoly Salyuk, Denis Kosmach, Denis Chernykh, Chris Stubbs, Dmitry Nicolsky, Vladimir Tumskoy & Örjan Gustafsson (2013)
http://www.nature.com/ngeo/journal/vaop/ncurrent/full/ngeo2007.html

Arctic storms speed up release of methane plumes, by Fred Pearce
http://www.newscientist.com/article/dn24639-arctic-storms-speed-up-release-of-methane-plumes.html

Twice as Much Methane Escaping Arctic Seafloor, by Becky Oskin
http://www.livescience.com/41476-more-arctic-seafloor-methane-found.html

Extensive methane venting to the atmosphere from sediments of the East Siberian Arctic shelf, by Natalia Shakhova, Igor Semiletov, Anatoly Salyuk, Vladimir Yusupov, Denis Kosmach, and Örjan Gustafsson, in: Science, 327, 1246-1250 (2010).
http://www.sciencemag.org/content/327/5970/1246.abstract

On carbon transport and fate in the East Siberian Arctic land–shelf–atmosphere system, by Semiletov et al. (2012)
http://iopscience.iop.org/1748-9326/7/1/015201

Intergovernmental Panel on Climate Change (IPCC), AR5 Working Group 1
http://www.climatechange2013.org/

Post by Sam Carana.

Highlights of EGU General Assembly 2012

If you will be attending the European Geosciences Union (EGU) General Assembly on April 25, 2012, make sure to attend, from 14:00 to 14:15 in room 23, the presentation:

Methane release from the East-Siberian Arctic Shelf and its connection with permafrost and hydrate destabilization: First results and potential future developments
by Natalia Shakhova and Igor Semiletov

The East Siberian Arctic Shelf (ESAS) is home to the world’s largest hydrocarbon stocks, which consist of natural gas, coal bed methane (CH4), and shallow Arctic hydrates. Until recently, the ESAS was not considered a CH4 source due to the supposed impermeability of sub-sea permafrost, which was thought to completely isolate the CH4 beneath from modern biogeochemical cycles.

However, the ESAS represents an enormous potential CH4 source that could be responsive to ongoing global warming. Such response could occur in substantially shorter time than that of terrestrial Arctic ecosystems, because sub-sea permafrost has experienced long-lasting destabilization initiated by its inundation during the Holocene ocean transgression. ESAS permafrost stability and integrity is key to whether sequestered ancient carbon escapes as the potent greenhouse gas CH4.

Recent data suggest the sub-sea permafrost is currently experiencing significant changes in its thermal regime. For example, our recent data obtained in the ESAS during the drilling expedition of 2011 showed no frozen sediments at all within the 53 m long drilling core at water temperatures varying from -0.6˚C to -1.3˚C.

Unfrozen sediments provide multiple potential CH4 migration pathways. We suggest that open taliks have formed beneath the areas underlain or influenced by the nearby occurrence of fault zones, under paleo-valleys, and beneath thaw lakes submerged several thousand years ago during the ocean transgression. Temporary gas migration pathways might occur subsequent to seismic and tectonic activity in an area, due to sediment settlement and subsidence; hydrates could destabilize due to development of thermokarst-related features or ice-scouring.

Recently obtained geophysical data identified numerous gas seeps, mostly above prominent reflectors, and the ubiquitous occurrence of shallow gas-charged sediments containing numerous gas chimneys, underscoring the likelihood that the ability of sub-sea permafrost to capture CH4 released from the seabed is failing.

Available data suggest the ESAS sub-sea permafrost is currently leaking a substantial amount of CH4. We propose that a few different types of CH4 exist, and are becoming involved in the modern carbon cycle due to permafrost destabilization in the ESAS: modern biogenic CH4 produced from ancient substrate, relatively old biogenic CH4 mobilized from hydrate deposits, and old thermogenic CH4 accumulated within seabed deposits. Isotopic data obtained by sampling CH4 in the water column and atmospheric CH4 in close proximity to the sea surface confirm the contribution from different sources, and demonstrate that the isotopic signature of CH4 from the ESAS can be used to create an interpretive plot for defining hydrates. CH4 fluxes could occur as numerous weak seeps, as large areas of strong bubble plumes, or as sites where CH4 releases are flare- or torch-like and the emissions are non-gradual.

Due to the shallow and oligotrophic nature of the ESAS, the majority of aqueous CH4 may avoid biological oxidation in the water column and escape to the atmosphere.

Further investigations should be focused on quantifying the total CH4 pool of the ESAS, improving our understanding of the mechanisms responsible for sub-sea permafrost destabilization and gas migration pathways formation, and decreasing uncertainties regarding the current CH4 emission mode and its future alteration by progressing permafrost degradation.

Geophysical Research Abstracts
Vol. 14, EGU2012-3877-1, 2012
EGU General Assembly 2012

Above presentation is part of the session:
Methane cycling in marine and terrestrial systems

which also features, as part of the poster program:
Display Time: Wednesday, 25 Apr 08:00–19:30
Attendance Time: Wednesday, 25 Apr 17:30–19:00
Poster Area BG

First drilling subsea permafrost in the southeastern Laptev Sea, the East Siberian Arctic Shelf: results and challenges
by Igor Semiletov, et al.
highlighting the following two challenges:

1) observed Arctic warming in early 21st century is stronger than predicted by several degrees, which may accelerate thaw release of methane from the upper seafloor layer by increasing bottom erosion and from deeper stratums (including hydrates) by sediment settlement and adjustment;

2) drastic sea ice shrinkage causes increase in storm activities and deepening of the wind-wave-mixing layer down to depth ~50 m that enhance methane release from the water column to the atmosphere.

Geophysical Research Abstracts
Vol. 14, EGU2012-3913, 2012
EGU General Assembly 2012

Rebuttal: Imminent collapse of Arctic sea ice drives danger of accelerated methane thaw

REBUTTAL:

         IMMINENT COLLAPSE OF ARCTIC SEA ICE DRIVES DANGER OF ACCELERATED METHANE THAW:

         Archer Errs in Dismissing Concern About Potential "Runaway" Feedback, Precautionary Principle Should Prevail  

by Professor Peter Wadhams

Image: Methane bubbles from: Sauter et al. dx.doi.org/10.1016/j.epsl.2006.01.041 

Background of rebuttal author -
Peter Wadhams Sc.D. is Professor of Ocean Physics at the University of Cambridge in the UK. He is an oceanographer and glaciologist involved in polar oceanographic and sea ice research and concerned with climate change processes in the polar regions He leads the Polar Ocean Physics group studying the effects of global warming on sea ice, icebergs and the polar oceans. This involves work in the Arctic and Antarctic from nuclear submarines, autonomous underwater vehicles (AUVs), icebreakers, aircraft and drifting ice camps. He has led over 40 polar field expeditions. His full background is available here: University of Cambridge DAMTP: Professor Peter Wadhams

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In a Jan. 4 post on "Real Climate" (1), David Archer addressed those who are raising concern about the speed of ice loss in the Arctic and the resultant potential for warming water temperatures to thaw frozen methane and release it as gas to the atmosphere. In essence, he dismissed such concern as a form of unfounded alarmism making "much ado about nothing". In this rebuttal, I would like to respectfully challenge this dismissive stance and assert that severe dangers are arising in the Arctic which instead call for the full attention of humanity.

The present thinning and retreat of Arctic sea ice is one of the most serious geophysical consequences of global warming and is causing a major change to the face of our planet. A challenging characteristic of the behaviour is that both the rate of retreat (especially in summer) and the rate of thinning in all seasons have greatly exceeded the predictions of most models. The sea ice cover of the Arctic Ocean, particularly in summer, has been in retreat since the 1950s at a rate of about 4% per decade which has recently increased to 10% per decade. More seriously, the thickness of the ice has diminished.

Satellites can track ice area, but ice thickness distribution can be most accurately measured by sonar from underneath the ice. Since 1971, I have been going to the Arctic in UK nuclear submarines, mapping the ice thickness using upward-looking sonar along the vessel’s track. U.S. submarines have also allowed such availablity. Opening these submarines to scientific work has been a marvelous service to climate research. It was thanks to submarines that I was able to show for the first time that the ice in the Arctic is thinning (in a 1990 paper in Nature (2), showing a 15% thickness loss in 11 years), and recent work from UK and US submarines now shows a loss of more than 43% in thickness between the 1970s and 2000s, averaged over the ocean as a whole (3). This is an enormous loss – nearly half of the ice thickness – and has changed the whole appearance of the ice cover. Most of the ice is now first-year rather than the formidable multi-year ice which used to prevail.

The thinning is caused by a mixture of reduced growth in winter, because of warmer temperatures and more heat in the underlying water column, and greater melt in summer. A change in the direction and speed of ice motion has also played a role, with the ice departing quicker from the Arctic Basin through Fram Strait rather than circulating many times inside the Arctic.

The summer (September) area of sea ice reached a record low in 2007, almost matched in 2011, but what is most serious is that the thinning continues. It is inevitable that very soon there will be a downward collapse of the summer area because the ice will just melt away. Already in 2007, measurements indicated that during the summer there were 2 metres of melt off the bottom of of ice floes in the Beaufort Sea, while the neighbouring first-year floes had only reached in 1.8 metres during winter – so all first-year ice was disappearing. This effect will become more important and will spread throughout the Arctic Basin.

There is currently disagreement about when the summer Arctic will become completely ice-free. It depends on what model is being employed. My own view is based on purely empirical grounds, that is, matching the observations of area from satellites with observations from submarines (combined with some modelling) of thickness to give us ice volume. If we think in volume terms instead of area terms, the downward trend is more than linear, in fact it is exponential, and if extrapolated it gives us an ice-free summer Arctic as early as 2015.

Others have talked of later dates, like 2030-2040, but I do not see how the trend of summer ice volume can possible permit this. Those who agree include W Maslowsky, a leading ice modeller (Naval Postgraduate School, Monterey), and the PIOMAS project at University of Washington which generated the data shown below (4).

Arctic sea ice volume decline graph by Wipneus based on PIOMAS data. 

Minimum volume of Arctic sea ice in midsummer, based on areas observed from satellites and thickness trends inferred from submarine observations. Extrapolation leads to a zero volume in 2015. It must be pointed out that this perspective stands in direct contradiction to very complacent statements about the Arctic sea ice from the IPCC in the AR4 report of April 2007 saying the sea ice was very likely to last beyond the end of the century.

The ice retreat is having major impact on the planet. The Arctic is the most rapidly warming region on Earth. It has become widely accepted that Arctic amplification of global warming is due to the albedo effect of sea ice retreat. The increased open water reduces the albedo (fraction of solar radiation reflected into space) and causes warming at high northern latitudes to be 2-4 times as fast as in the tropics, with enormous implications for climatic instability. Secondly, the summer retreat of the ice from the wide Arctic continental shelves (particularly the East Siberian Sea) allows the shallow surface layer to warm up, bringing temperatures of up to 5 degrees C right down to the seabed.

Quantification of this affect has only very recently been attempted, in a paper to the 2011 AGU by Hudson (5). The startling conclusion is that the rate of warming of the Arctic could double or triple, once the Arctic Ocean is ice-free in September. And it could double or triple again, once the ocean is ice-free for half the year. But the timescale makes this all the more worrying.

The scientific community has drawn attention to the risk of dangerous climate change if the world does not reduce emissions of carbon dioxide - a worthy and critical objective. However, I wish to point toward a much more immediate problem that does not seem to be recognised among the climate change community at large: This is the problem of rapid retreat of Arctic sea ice, and likely consequence of catastrophic methane feedback.

These rapidly warming temperatures are accelerating the melt of offshore permafrost, releasing methane trapped as methane hydrates and causing large plumes of methane to appear all over the summer Arctic shelves (observed for the last 2-3 summers by Semiletov and colleagues on joint University of Alaska – Far Eastern Research Institute cruises). Methane levels in the Arctic atmosphere have started to rise (measured by Dr Leonid Yurganov, Johns Hopkins University) after being stable for some years. As methane is a very powerful, if short lived, greenhouse gas, this will give a strong upward kick to global warming.

According to research crew leader Igor Semiletov:

"We carried out checks at about 115 stationary points and discovered methane fields of a fantastic scale - I think on a scale not seen before.... This is the first time we've found continuous, powerful and impressive seeping structures more than 1,000 meters in diameter." (6)

Semiletov has also described how warmer temperatures are making their way down to the bottom of the shallow seabeds in the Arctic continental shelves:

"When ice has gone, there are stronger winds and waves and a deeper mixing of water which causes the comparatively warm upper layer to mix with water at deeper levels. There are already studies which confirm that in some areas, bottom temperature in summer is 2 to 3 degrees above zero celsius (freezing). As this warming spreads to a larger area, the more that shelf-based permafrost will thaw." (7)

There have been warnings that a major methane outbreak may be imminent.

In a piece Archer co-authored in 2009, he acknowledged both the significant warming power of methane and the fragile and "intrinsically vulnerable" nature of hydrates:

"There are concerns that climate change could trigger significant methane releases from hydrates and thus could lead to strong positive carbon–climate feedbacks. .... Methane hydrate seems intrinsically vulnerable on Earth nowhere at the Earth's surface is it stable to melting and release of the methane." (8)

In this same piece, Archer affirms another key factor:

"Rapid warming well above the global average makes the Arctic hydrates particularly vulnerable to climate change." (8)

Archer clearly acknowledges the vulnerability of methane hydrates to thawing in response to rising Arctic temperatures. Given that ice loss is accelerating, which in turn will only accelerate that temperature rise through the albedo effect, one has to wonder why he does not perceive an imminent and urgent crisis. Ira Leifer - methane specialist at the Marine Science Institute at Univ. of Calif - Santa Barbara - describes the mechanics of a "runaway" methane feedback:

"A runaway feedback effect would be where methane comes out of the ocean into the atmosphere leading to warming, leading to warmer oceans and more methane coming out, causing an accelerated rate of warming in what one could describe as a runaway train." (9)

Given that this "train" would be one way and feed upon itself in a way that might well be unstoppable by humanity, it would seem to be a classic case where the precautionary principle should immediately be invoked. When Archer dismisses the legitimate concern that conditions in the Arctic are approaching a potentially catastrophic tipping point, he is deflecting away a vitally important perspective that needs to be communicated to the world's policymakers. I strongly urge Archer to re-consider his position.

It is also my understanding that one of the recipients of Archer's "dismissal" charge was documentary film-maker Gary Houser. Houser had submitted an earlier rebuttal to Archer - based on his interviews with scientists related to a program on the issue of Arctic methane - which was rejected by "Real Climate" on the grounds that he himself is not an accredited scientist. I have read his rebuttal and wish to link to it here (10), as I believe it contains points of merit I do not have space to address here.

Footnoted sources and links:
(1) RealClimate: Much ado about methane
(2) Wadhams: 1990 Wadhams, P. Evidence for thinning of the Arctic ice cover north of Greenland. Nature, Lond., vol 345, 795-797.
(3) Wadhams: Arctic Sea Ice Thickness: Past, Present & Future - European ...
(4) PIOMAS graph link: http://neven1.typepad.com/.a/6a0133f03a1e37970b0153920ddd12970b-pi
(5) Hudson: http://www.agu.org/pubs/crossref/2011/2011JD015804.shtml
(6) UK Independent, Dec.13, 2011 Vast methane 'plumes' seen in Arctic ocean as sea ice retreats ...
(7) Documentary interview with Semiletov: www.590films.org/methane.html
(8) Archer, co-author Gas hydrates: entrance to a methane age or climate ... - IOPscience
(9) Documentary interview with Leifer: www.590films.org/methane.html
(10) Houser rebuttal to Archer, link: http://arctic-news.blogspot.com/2012/02/rebuttal-david-archer-wrong-to-dismiss.html

Professor Peter Wadhams is author of a recent science paper entitled "Arctic Ice Cover, Ice Thickness, and Tipping Points". It was published in AMBIO: A Journal of the Human Environment produced by the Royal Swedish Academy of Sciences. Link to abstract and full text preview of published article: Arctic Ice Cover, Ice Thickness and Tipping Points - SpringerLink This paper was written for the Arctic Tipping Points Project (www.eu-atp.org) - a large scale integrating project funded by the European Union 7th Framework Programme.

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Video: East Siberian Arctic Shelf Expedition 2011

East Siberian Arctic Shelf Expedition 2011.

In an interview published February 9, 2012, expedition leader Dr. Igor Semiletov said: "the methane release that we have identified in the Arctic is both unprecedented in terms of its volume and has the potential to increase greatly if warming trends continue."

Video uploaded by the International Arctic Research Center (IARC) at the University of Alaska Fairbanks (UAF) at Youtube:
http://www.youtube.com/watch?v=b73wLHoiQyI

Also view map of the study area explored during the expedition.